You guys could always make yourselves some compilation cds! A complete list of the music from mostly every ep (except the latter part of s3) is up at alias-tv.com
I have four Alias Mix CDs and they are always on in my car. I love how the show's music crosses so many genres. You'll get like ACDC and then Peter Gabriel and then Patsy Cline, or like Limp Biskit followed by Cat Stevens and Lucinda Williams. Hee hee.
I adore my comp cds because hearing the songs makes me remember the scene each song is from. And it's funny how now I always associate those songs with the Alias scene they come from. The highlights off the top of my head are No Man's Woman, Angel, Diggin Your Scene, Songbird, Shelter From the Storm, River, Back in Black, Walk On, Emotional Rescue, Serious Juju (YAY Marshall!) Freedom, Cannonball, Bleed To Love Her, Saturday Afternoons in 1969, She's Got You, Bad Day, and Sonething Else. And if anyone can tell me what scenes these are all from, you get a cookie!
If anyone wants me to send them songfiles of any Alias songs (I have about 70 of them), or a copy of my winamp Alias playlist, IM me at evergreenspy on aim, I'd be happy to share the AliasMusicLove